Arsenal have played Valencia CF 7 times in competitive football, winning 3, drawing 2 and losing 2, first meeting on 14 May 1980 and most recently on 9 May 2019. Every meeting is listed below.
| Date | Season | Competition | Venue | Opponent | Score | Scorers | Att |
|---|---|---|---|---|---|---|---|
| 14 May 1980 | 1979–80 | Cup Winners' Cup | H | Valencia CF | 0–0 | ||
| 4 Apr 2001 | 2000–01 | Champions League | H | Valencia CF | 2–1 | Thierry Henry 58, Ray Parlour 60 | 35,104 |
| 17 Apr 2001 | 2000–01 | Champions League | A | Valencia CF | 0–1 | 48,000 | |
| 10 Dec 2002 | 2002–03 | Champions League | H | Valencia CF | 0–0 | 34,793 | |
| 19 Mar 2003 | 2002–03 | Champions League | A | Valencia CF | 1–2 | Thierry Henry 49 | 50,000 |
| 2 May 2019 | 2018–19 | Europa League | H | Valencia CF | 3–1 | Alexandre Lacazette 18, Alexandre Lacazette 26, Pierre-Emerick Aubameyang 90+1 | 58,969 |
| 9 May 2019 | 2018–19 | Europa League | A | Valencia CF | 4–2 | Pierre-Emerick Aubameyang 17, Alexandre Lacazette 50, Pierre-Emerick Aubameyang 69, Pierre-Emerick Aubameyang 88 | 44,481 |