Arsenal have played Real Madrid C.F. 4 times in competitive football, winning 3, drawing 1 and losing 0, first meeting on 21 Feb 2006 and most recently on 16 Apr 2025. Every meeting is listed below.
| Date | Season | Competition | Venue | Opponent | Score | Scorers | Att |
|---|---|---|---|---|---|---|---|
| 21 Feb 2006 | 2005–06 | Champions League | A | Real Madrid C.F. | 1–0 | Thierry Henry 47 | 80,000 |
| 8 Mar 2006 | 2005–06 | Champions League | H | Real Madrid C.F. | 0–0 | 35,487 | |
| 8 Apr 2025 | 2024–25 | Champions League | H | Real Madrid C.F. | 3–0 | Declan Rice 58, Declan Rice 70, Mikel Merino 75 | 60,110 |
| 16 Apr 2025 | 2024–25 | Champions League | A | Real Madrid C.F. | 2–1 | Bukayo Saka 65, Gabriel Martinelli 90+3 | 77,073 |