Arsenal have played Port Vale 23 times in competitive football, winning 13, drawing 6 and losing 4, first meeting on 25 Dec 1893 and most recently on 24 Sep 2025. Every meeting is listed below.
| Date | Season | Competition | Venue | Opponent | Score | Scorers | Att |
|---|---|---|---|---|---|---|---|
| 25 Dec 1893 | 1893–94 | Second Division | H | Port Vale | 4–1 | Gavin Crawford, James Henderson, Walter Shaw, Charles Booth | |
| 6 Jan 1894 | 1893–94 | Second Division | A | Port Vale | 1–2 | Arthur Elliott | |
| 25 Dec 1894 | 1894–95 | Second Division | H | Port Vale | 7–0 | Fred Davis, James Henderson, Robert Buchanan, O'Brien, O'Brien, O'Brien, William Sharpe | |
| 19 Jan 1895 | 1894–95 | Second Division | A | Port Vale | 1–0 | Gavin Crawford | |
| 25 Dec 1895 | 1895–96 | Second Division | H | Port Vale | 2–1 | Peter Mortimer, Robert Buchanan | |
| 15 Feb 1896 | 1895–96 | Second Division | A | Port Vale | 2–0 | Haywood, Henry Boyd | |
| 5 Sep 1898 | 1898–99 | Second Division | A | Port Vale | 0–3 | ||
| 25 Feb 1899 | 1898–99 | Second Division | H | Port Vale | 1–0 | Herbert Shaw | |
| 16 Sep 1899 | 1899–00 | Second Division | H | Port Vale | 1–0 | Moses Sanders | |
| 13 Jan 1900 | 1899–00 | Second Division | A | Port Vale | 1–1 | Ralph Gaudie | |
| 8 Dec 1900 | 1900–01 | Second Division | H | Port Vale | 3–0 | John Blackwood, Walter Place, Walter Place | |
| 13 Apr 1901 | 1900–01 | Second Division | A | Port Vale | 0–1 | ||
| 28 Sep 1901 | 1901–02 | Second Division | A | Port Vale | 0–1 | ||
| 26 Dec 1901 | 1901–02 | Second Division | H | Port Vale | 3–1 | Tommy Briercliffe, Sandy Main, Bill Gooing | |
| 13 Sep 1902 | 1902–03 | Second Division | H | Port Vale | 3–0 | John Dick, Tommy Briercliffe, Tim Coleman | |
| 10 Jan 1903 | 1902–03 | Second Division | A | Port Vale | 1–1 | Tommy Briercliffe | |
| 24 Oct 1903 | 1903–04 | Second Division | A | Port Vale | 3–2 | Tommy Briercliffe, Bill Gooing, Tommy Shanks | |
| 25 Apr 1904 | 1903–04 | Second Division | H | Port Vale | 0–0 | ||
| 29 Jan 1927 | 1926–27 | FA Cup | A | Port Vale | 2–2 | Jimmy Brain, Charlie Buchan | |
| 2 Feb 1927 | 1926–27 | FA Cup | H | Port Vale | 1–0 | Charlie Buchan | |
| 3 Jan 1998 | 1997–98 | FA Cup | H | Port Vale | 0–0 | 37,471 | |
| 14 Jan 1998 | 1997–98 | FA Cup | A | Port Vale | 1–1 | Dennis Bergkamp 100 | 14,964 |
| 24 Sep 2025 | 2025–26 | League Cup | A | Port Vale | 2–0 | Eberechi Eze 8, Leandro Trossard 86 | 16,326 |
See also: the Port Vale archive and Port Vale v Arsenal.